If the coefficients in the displayed representation of v are unique, suppose a non-zero relation
c1u1+⋯+cnun=0
exists. Then
v=(λ1+c1)u1+⋯+(λn+cn)un
is another representation of v. Since some cj=0, the two representations are different, a contradiction. Thus the set is linearly independent. Conversely, suppose
v=λ1u1+⋯+λnun=α1u1+⋯+αnun.
Subtracting gives
(λ1−α1)u1+⋯+(λn−αn)un=0.
Independence forces λj−αj=0 for every j, so the two representations are the same.
If μ=0, then v is a linear combination of the vectors in S, contradicting v∈/span(S). Hence μ=0 and the independence of S forces λ1=⋯=λn=0. Therefore S∪{v} is linearly independent.